A Convenient Synthesis of Perfluoroalkylated Indolizinylphosphonates

Yanchang Shen; Yuming Zhang; Guo-Fang Jiang

doi:10.1055/s-2002-25763

SHORTPAPER

A Convenient Synthesis of Perfluoroalkylated Indolizinylphosphonates

Yanchang Shen*, Yuming Zhang, Guo-Fang Jiang
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Academia Sinica, 354 Fenglin Lu, Shanghai 200032, China
Fax: +86(21)64166128; e-Mail: shenyc@pub.sioc.ac.cn;

Abstract

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Abstract

A convenient method for the synthesis of perfluoroalkylated indolizinyl-phosphonates via the 1,3-cycloaddition of pyridinium N-ylide and perfluoroalkynyl phosphonate in 49-77% yields is described.

Key words

perfluoroalkylated indolizinylphosphonate - 1,3-cycloaddition - pyridinium N-ylide - perfluoroalkynylphosphonate

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References

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