Synthesis, Table of Contents SHORTPAPER © Georg Thieme Verlag Stuttgart · New York Rhodium(I)-Catalyzed 1,2- and 1,4-Addition of Aryltriethoxysilanes to Carbonyl Compounds under Aqueous Basic Conditions Miki Murata*, Ryuta Shimazaki, Masanori Ishikura, Shinji Watanabe, Yuzuru Masuda*Department of Materials Science, Kitami Institute of Technology, Kitami, 090-8507, JapanFax: +81(157)264973; e-Mail: muratamk@mail.kitami-it.ac.jp; e-Mail: masudayz@mail.kitami-it.ac.jp; Recommend Article Abstract Buy Article All articles of this category Abstract Aryltriethoxysilanes add to aldehydes and α,β-unsaturated carbonyl compounds in high yield in the presence of a rhodium(I) catalyst and aqueous sodium hydroxide. Key words rhodium - addition reactions - silicon - arylations - carbonyl compounds Full Text References References 1a Tamao K. Kobayashi K. Ito Y. Tetrahedron Lett. 1989, 30: 6051 1b Shibata K. Miyazawa K. Goto Y. Chem. Commun. 1997, 1309 1c Mowery ME. DeShong P. J. Org. Chem. 1999, 64: 1684 1d Mowery ME. DeShong P. Org. Lett. 1999, 1: 2140 1e Lee HM. Nolan SP. Org. Lett. 2000, 2: 2053 2a Lam PYS. Deudon S. Averill KM. Li R. He MY. DeShong P. Clark CG. J. Am. Chem. Soc. 2000, 122: 7600 2b Lam PYS. Deudon S. Hauptman E. Clark CG. Tetrahedron Lett. 2001, 42: 2427 3 Murata M. Shimazaki R. Watanabe S. Masuda Y. Synthesis 2001, 2231 4a Oi S. Moro M. Inoue Y. Chem. Commun. 1997, 1621 4b Oi S. Moro M. Ono S. Inoue Y. Chem. Lett. 1998, 83 4c Oi S. Moro M. Fukuhara H. Kawanishi H. Inoue Y. Tetrahedron Lett. 1999, 40: 9259 5a Sakai M. Hayashi H. Miyaura N. Organometallics 1997, 16: 4229 5b Sakai M. Ueda M. Miyaura N. Angew. Chem., Int. Ed. 1998, 37: 3279 5c Ueda M. Miyaura N. J. Organomet. Chem. 2000, 595: 31 6 Oi S. Moro M. Inoue Y. Organometallics 2001, 20: 1036 7 Fujii T. Koike T. Mori A. Osakada K. Synlett 2002, 298 8 Huang TS. Li CJ. Chem. Commun. 2001, 2348 9a Mori A. Danda Y. Fujii T. Hirabayashi K. Osakada K. J. Am. Chem. Soc. 2001, 123: 10774 9b Koike T. Du X. Mori A. Osakada K. Synlett 2002, 301 9c Fujii T. Koike T. Mori A. Osakada K. Synlett 2002, 295 10 Oi S. Honma Y. Inoue Y. Org. Lett. 2002, 4: 669 11a Murata M. Suzuki K. Watanabe S. Masuda Y. J. Org. Chem. 1997, 62: 8569 11b Murata M. Watanabe S. Masuda Y. Tetrahedron Lett. 1999, 40: 9255 11c Manoso AS. DeShong P. J. Org. Chem. 2001, 66: 7455 12a Usón R. Oro LA. Cabeza JA. Inorg. Synth. 1985, 23: 126 12b Agarawal SK. Mehrotra RC. J. Indian Chem. Soc. 1985, 62: 805 13a Hatanaka Y. Hiyama T. Synlett 1991, 845 13b Hiyama T. In Metal-Catalyzed Cross-Coupling Reactions Diederich F. Stang PJ. Wiley-VCH; Weinhein: 1998. p.421
