Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000084.xml
Synthesis 2002(6): 0717-0719
DOI: 10.1055/s-2002-25764
DOI: 10.1055/s-2002-25764
SHORTPAPER
© Georg Thieme Verlag Stuttgart · New York
Rhodium(I)-Catalyzed 1,2- and 1,4-Addition of Aryltriethoxysilanes to Carbonyl Compounds under Aqueous Basic Conditions
Further Information
Received
15 February 2002
Publication Date:
26 April 2002 (online)
Publication History
Publication Date:
26 April 2002 (online)
Abstract
Aryltriethoxysilanes add to aldehydes and α,β-unsaturated carbonyl compounds in high yield in the presence of a rhodium(I) catalyst and aqueous sodium hydroxide.
Key words
rhodium - addition reactions - silicon - arylations - carbonyl compounds
-
1a
Tamao K.Kobayashi K.Ito Y. Tetrahedron Lett. 1989, 30: 6051 -
1b
Shibata K.Miyazawa K.Goto Y. Chem. Commun. 1997, 1309 -
1c
Mowery ME.DeShong P. J. Org. Chem. 1999, 64: 1684 -
1d
Mowery ME.DeShong P. Org. Lett. 1999, 1: 2140 -
1e
Lee HM.Nolan SP. Org. Lett. 2000, 2: 2053 -
2a
Lam PYS.Deudon S.Averill KM.Li R.He MY.DeShong P.Clark CG. J. Am. Chem. Soc. 2000, 122: 7600 -
2b
Lam PYS.Deudon S.Hauptman E.Clark CG. Tetrahedron Lett. 2001, 42: 2427 - 3
Murata M.Shimazaki R.Watanabe S.Masuda Y. Synthesis 2001, 2231 -
4a
Oi S.Moro M.Inoue Y. Chem. Commun. 1997, 1621 -
4b
Oi S.Moro M.Ono S.Inoue Y. Chem. Lett. 1998, 83 -
4c
Oi S.Moro M.Fukuhara H.Kawanishi H.Inoue Y. Tetrahedron Lett. 1999, 40: 9259 -
5a
Sakai M.Hayashi H.Miyaura N. Organometallics 1997, 16: 4229 -
5b
Sakai M.Ueda M.Miyaura N. Angew. Chem., Int. Ed. 1998, 37: 3279 -
5c
Ueda M.Miyaura N. J. Organomet. Chem. 2000, 595: 31 - 6
Oi S.Moro M.Inoue Y. Organometallics 2001, 20: 1036 - 7
Fujii T.Koike T.Mori A.Osakada K. Synlett 2002, 298 - 8
Huang TS.Li CJ. Chem. Commun. 2001, 2348 -
9a
Mori A.Danda Y.Fujii T.Hirabayashi K.Osakada K. J. Am. Chem. Soc. 2001, 123: 10774 -
9b
Koike T.Du X.Mori A.Osakada K. Synlett 2002, 301 -
9c
Fujii T.Koike T.Mori A.Osakada K. Synlett 2002, 295 - 10
Oi S.Honma Y.Inoue Y. Org. Lett. 2002, 4: 669 -
11a
Murata M.Suzuki K.Watanabe S.Masuda Y. J. Org. Chem. 1997, 62: 8569 -
11b
Murata M.Watanabe S.Masuda Y. Tetrahedron Lett. 1999, 40: 9255 -
11c
Manoso AS.DeShong P. J. Org. Chem. 2001, 66: 7455 -
12a
Usón R.Oro LA.Cabeza JA. Inorg. Synth. 1985, 23: 126 -
12b
Agarawal SK.Mehrotra RC. J. Indian Chem. Soc. 1985, 62: 805 -
13a
Hatanaka Y.Hiyama T. Synlett 1991, 845 -
13b
Hiyama T. In Metal-Catalyzed Cross-Coupling ReactionsDiederich F.Stang PJ. Wiley-VCH; Weinhein: 1998. p.421