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Synthesis 2002(16): 2383-2386
DOI: 10.1055/s-2002-35216
DOI: 10.1055/s-2002-35216
PAPER
© Georg Thieme Verlag Stuttgart · New York
Lithium Perchlorate Catalyzed Regioselective Ring Opening of Aziridines with Sodium Azide and Sodium Cyanide
Further Information
Publication History
Received
30 April 2002
Publication Date:
04 November 2002 (online)


Abstract
Aziridines react smoothly with sodium azide and sodium cyanide in the presence of catalytic amount of lithium perchlorate under essentially mild and neutral reaction conditions to afford the corresponding β-azido and β-cyanoamines in high yields with high regioselectivity.
Keywords
lithium perchlorate - aziridines - regioselective - β-azidoamines