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Synthesis 2003(3): 0371-0374
DOI: 10.1055/s-2003-37348
PAPER
© Georg Thieme Verlag Stuttgart · New York

Facile Synthesis of Novel 2-Styrylbenzothiazoles Containing Crown Ether Moieties

Olga A. Fedorova*, Elena N. Andryukhina, Sergey P. Gromov
Photochemistry Center of Russian Academy of Sciences, ul. Novatorov 7a, Moscow 119421, Russia
Fax: +7(095)9361255; e-Mail: fedorova@photonics.ru;
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Publication History

Received 27 March 2002
Publication Date:
19 February 2003 (online)

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Abstract

Novel 2-styrylbenzothiazoles containing crown ether moieties with different combinations of O, S, and N atoms were prepared by condensation of 2-methylbenzothiazole with formyl derivatives of benzocrown ethers in the presence of alkali metal alkoxides or by Wittig reaction. The role of complex formation in these syntheses is discussed.

Key words

2-styrylbenzothiazole - crown ethers - condensation - Wittig reaction - complex formation

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