Synthesis of Organic Nitrogen Heterocyclic Salts

M’hamed Chahma; Catherine Combellas; André Thiébault

doi:10.1055/s-2004-815931

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Synthesis 2004(4): 517-520
DOI: 10.1055/s-2004-815931

PAPER

Synthesis of Organic Nitrogen Heterocyclic Salts

M’hamed Chahma*^a, Catherine Combellas^b, André Thiébault^b
^a University of Victoria, Department of Chemistry, P.O. Box 3065, Victoria, BC, Canada, V8W 3V6
Fax: +1(250)7217147; e-Mail: chahma@uvic.ca;
^b Laboratoire Environnement et Chimie Analytique, 10 rue Vauquelin 75231 Paris cedex 05, France

Further Information

Publication History

Received 25 September 2003
Publication Date:
26 January 2004 (online)

Abstract
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Abstract

New (pyrrolyl)-pyridinium and quinolinium salts have been prepared selectively in high yields by reacting (pyrrolyl)-pyridine or -quinoline and their derivatives with CF₃SO₃CH₃ in CH₂Cl₂. No methylation of the nitrogen of pyrrole was observed. Preliminary investigations revealed that these salts show a good response as nonlinear optics.

Key words

pyrrole - polypyrrole - pyridinium - quinolinium - methylation - S_RN1 - Hyper-Rayleigh Scattering

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