Synlett 2004(6): 1122-1122  
DOI: 10.1055/s-2004-822910
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© Georg Thieme Verlag Stuttgart · New York

Transition Metal-based Lewis Acid Catalyzed Ring Opening of Epoxides Using Amines Under Solvent-Free Conditions



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Publikationsdatum:
14. Juni 2004 (online)

Zhao Pei-Qing. Xu Li-Wen. Xia Chun-Gu.

The schemes of entry 7 and entry 10 in Table 1 were incorrect, the correct figures are shown as follows:

Table 1 Ring Opening of Various Epoxides with Amines Catalyzed by SnCl4·5H2O under Solvent-Free Conditions

Entry Epoxides Products Temperature (°C) Time (h) Yields (%)
6

50 10 91
(96:4)
7

50 10 83
(97:3)
9

50 6 87
(90:10)
10

50 6 78
(86:14)