Preparation of Nitrogen-Containing 25-Membered Pentaolefinic Macrocycles: (E,E,E,E,E)-1,6,11,16,21-Penta(arylsulfonyl)-1,6,11,16,21-pentaazacyclopentacosa-3,8,13,18,23-pentaenes

Abstract

A stepwise preparation of a series of nitrogen-containing 25-membered pentaolefinic macrocycles is presented. The corresponding arenesulfonamides and trans-1,4-dibromo-2-butene served as precursors for the synthesis.

Key words

alkenes - heterocycles - macrocycles - sulfonamides

References

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• 13b

  It gave correct elemental analysis.

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8

Crystallographic data (excluding structure factors) for the structure in this paper has been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 230218. Copies of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK [fax: [phone] or e-mail: [e-mail]].