Solvent-Free Synthesis of γ-Nitroketones and γ-Nitroesters Promoted by the Ionic Liquid/K2CO3 Catalytic System

Sergey G. Zlotin; Andrey V. Bogolyubov; Galina V. Kryshtal; Galina M. Zhdankina; Marina I. Struchkova; Vladimir A. Tartakovsky

doi:10.1055/s-2006-950306

PAPER

Solvent-Free Synthesis of γ-Nitroketones and γ-Nitroesters Promoted by the Ionic Liquid/K₂CO₃ Catalytic System

Sergey G. Zlotin*, Andrey V. Bogolyubov, Galina V. Kryshtal, Galina M. Zhdankina, Marina I. Struchkova, Vladimir A. Tartakovsky
N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prosp. 47, Moscow 119991, Russia
Fax: +7(495)1355328; e-Mail: zlotin@ioc.ac.ru;

Abstract

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Abstract

A convenient solvent-free synthesis of γ-nitroketones and γ-nitroesters based on the reaction of nitroalkanes with α,β-unsaturated carbonyl compounds in the ultrasonically activated heterogeneous catalytic system 1-butyl-3-methylimidazolium tetra-fluoroborate ([bmim][BF₄])/K₂CO₃ has been developed. The system retained its catalytic activity over three reaction cycles.

Key words

Michael additions - ionic liquids - catalysis - esters - ketones

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References

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