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Synthesis 2007(3): 389-392
DOI: 10.1055/s-2006-958961
DOI: 10.1055/s-2006-958961
PAPER
© Georg Thieme Verlag Stuttgart · New York
A General and Efficient Synthesis of Nitrogen-Substituted Ferrocenes
Further Information
Received
6 October 2006
Publication Date:
21 December 2006 (online)
Publication History
Publication Date:
21 December 2006 (online)
Abstract
Copper(I) iodide mediated Ullmann-type coupling reactions of iodoferrocene and 1,1′-diiodoferrocene has been used to synthesize N-substituted ferrocenes that are difficult to obtain by classical methods. In this manner, a range of Fc-[N]-R-type compounds have been prepared in moderate to good yields.
Key words
copper - cross-coupling - ferrocene - heterocycle - Ullmann coupling
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