[3+2] Cycloaddition of Diazocarbonyl Compounds to 1,1-Dinitroethenes: Synthesis of Functionalized gem-Dinitrocyclopropanes

Abstract

The synthesis of functionalized gem-dinitrocyclopropanes via [3+2] cycloaddition of diazocarbonyl compounds with 1,1-dinitroethenes [in some cases in the presence of Mo(CO)₆ as catalyst] has been developed.

Key words

[3+2] cycloaddition - α-diazocarbonyl compound - 1,1-dinitroethene - 1,1-dinitrocyclopropane - hexacarbonylmolybdenum

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