DOI: 10.1055/s-00000084

Synthesis

Issue 15 · Volume 49 · August 2017 DOI: 10.1055/s-007-34462

Synform

A123
Zanda, Matteo: SYNFORM ISSUE 2017/08

preface

I
Knochel, Paul: Preface – Special Issue Dedicated to Professor Herbert Mayr

review

3183
Evano, Gwilherm; Lecomte, Morgan; Thilmany, Pierre; Theunissen, Cédric: Keteniminium Ions: Unique and Versatile Reactive Intermediates for Chemical Synthesis
https://www.thieme-connect.de/media/synthesis/201715/i_z0326_ga_10-1055_s-0036-1588452.jpg

short review

3215
Chen, Yi-Hung; Ellwart, Mario; Malakhov, Vladimir; Knochel, Paul: Solid Organozinc Pivalates: A New Class of Zinc Organometallics with Greatly Enhanced Air- and Moisture-Stability
https://www.thieme-connect.de/media/synthesis/201715/i_m0222_ga_10-1055_s-0036-1588843.jpg
3224
Breugst, Martin; von der Heiden, Daniel; Schmauck, Julie: Novel Noncovalent Interactions in Catalysis: A Focus on Halogen, Chalcogen, and Anion-π Bonding
https://www.thieme-connect.de/media/synthesis/201715/i_z0277_ga_10-1055_s-0036-1588838.gif
3237
Bartolo, Nicole D.; Read, Jacquelyne A.; Valentín, Elizabeth M.; Woerpel, K. A.: Reactions of Allylmagnesium Halides with Carbonyl Compounds: Reactivity, Structure, and Mechanism
https://www.thieme-connect.de/media/synthesis/201715/i_z0273_ga_10-1055_s-0036-1588427.gif
3247
Mąkosza, Mieczysław: How Does Nucleophilic Aromatic Substitution in Nitroarenes Really Proceed: General Mechanism
https://www.thieme-connect.de/media/synthesis/201715/i_z0278_ga_10-1055_s-0036-1588444.gif
3255
Tabolin, Andrey A.; Sukhorukov, Alexey Yu.; Ioffe, Sema L.; Dilman, Alexander D.: Recent Advances in the Synthesis and Chemistry of Nitronates
https://www.thieme-connect.de/media/synthesis/201715/i_z0279_ga_10-1055_s-0036-1589063.gif
3269
Parchomyk, Tobias; Koszinowski, Konrad: Iron-Catalyzed Cross-Coupling: Mechanistic Insight for Rational Applications in Synthesis
https://www.thieme-connect.de/media/synthesis/201715/i_z0280_ga_10-1055_s-0036-1588428.gif
3281
Dana, Suman; Ramakrishna, Isai; Baidya, Mahiuddin: Ambident Reactivity of Nitroso Compounds for Direct Amination and Hydroxylation of Carbonyls
https://www.thieme-connect.de/media/synthesis/201715/i_z0290_ga_10-1055_s-0036-1590793.gif
3291
Reissig, Hans-Ulrich; Zimmer, Reinhold: Cyclizations of Alkoxyallenes: Mechanisms, Intermediates, ­Products – A Personal Account on Solved and Unsolved Problems with Unique Allene Building Blocks
https://www.thieme-connect.de/media/synthesis/201715/i_z0299_ga_10-1055_s-0036-1588846.gif
3303
Hartley, Will C.; O’Riordan, Timothy J. C.; Smith, Andrew D.: Aryloxide-Promoted Catalyst Turnover in Lewis Base Organo­catalysis
https://www.thieme-connect.de/media/synthesis/201715/i_z0313_ga_10-1055_s-0036-1589047.gif
3311
Fantin, Marco; Lorandi, Francesca; Gennaro, Armando; Isse, Abdirisak A.; Matyjaszewski, Krzysztof: Electron Transfer Reactions in Atom Transfer Radical Polymerization
https://www.thieme-connect.de/media/synthesis/201715/i_z0322_ga_10-1055_s-0036-1588873.gif
3323
Armstrong, Roly J.; Aggarwal, Varinder K.: 50 Years of Zweifel Olefination: A Transition-Metal-Free Coupling
https://www.thieme-connect.de/media/synthesis/201715/i_z0328_ga_10-1055_s-0036-1589046.gif
3337
Abe, Manabu; Chitose, Youhei; Jakkampudi, Satish; Thuy, Pham Thi Thu; Lin, Qianghua; Van, Bui Thi; Yamada, Ayato; Oyama, Ryoko; Sasaki, Miyu; Katan, Claudine: Design and Synthesis of Two-Photon Responsive Chromophores for Near-Infrared Light-Induced Uncaging Reactions
https://www.thieme-connect.de/media/synthesis/201715/i_z0330_ga_10-1055_s-0036-1590813.gif
3347
Micheletti, Gabriele; Boga, Carla: Nucleophile/Electrophile Combinations in Aromatic Substitution: From Wheland to Wheland–Meisenheimer Intermediates Using Strongly Activated Arenes
https://www.thieme-connect.de/media/synthesis/201715/i_z0333_ga_10-1055_s-0036-1588490.gif
3357
Zhao, Rong; Chang, Denghu; Shi, Lei: Recent Advances in Cyclic Diacyl Peroxides: Reactivity and Selectivity Enhancement Brought by the Cyclic Structure
https://www.thieme-connect.de/media/synthesis/201715/i_z0281_ga_10-1055_s-0036-1588458.gif
3366
Asahara, Haruyasu: Recent Advances in the Carbon–Carbon Bond-Forming Reactions of N-Acylketimines
https://www.thieme-connect.de/media/synthesis/201715/i_z0287_ga_10-1055_s-0036-1590814.gif
3377
Maji, Biplab; Barman, Milan K.: Recent Developments of Manganese Complexes for Catalytic Hydrogenation and Dehydrogenation Reactions
https://www.thieme-connect.de/media/synthesis/201715/i_z0289_ga_10-1055_s-0036-1590818.jpg
3394
Krishnamoorthy, Sankarganesh; Prakash, G. K. Surya: Silicon-Based Reagents for Difluoromethylation and Difluoromethylenation Reactions
https://www.thieme-connect.de/media/synthesis/201715/i_z0300_ga_10-1055_s-0036-1588489.jpg
3407
Gao, Pin; Gu, Yu-Rui; Duan, Xin-Hua: Direct C–H Functionalization of Heteroarenes via Redox-Neutral Radical Process: A Facile Route to C–C Bonds Formation
https://www.thieme-connect.de/media/synthesis/201715/i_z0301_ga_10-1055_s-0036-1588493.gif
3422
Denegri, Bernard; Matić, Mirela; Kronja, Olga: Impact of Electronic Effects on the Nucleofugality of Leaving Groups
https://www.thieme-connect.de/media/synthesis/201715/i_z0318_ga_10-1055_s-0036-1590792.gif
3433
Gualandi, Andrea; Mengozzi, Luca; Cozzi, Pier Giorgio: Stereoselective SN1-Type Reaction of Enols and Enolates
https://www.thieme-connect.de/media/synthesis/201715/i_z0321_ga_10-1055_s-0036-1588871.gif
3444
Quint, Valentin; Noël-Duchesneau, Ludovik; Lagadic, Elodie; Morlet-Savary, Fabrice; Lalevée, Jacques; Gaumont, Annie- Claude; Lakhdar, Sami: Metal-Free Generation of Phosphorus-Centered Radicals for the Synthesis of Phosphorus-Based Heterocycles: A Personal Account
https://www.thieme-connect.de/media/synthesis/201715/i_z0364_ga_10-1055_s-0036-1588499.gif

paper

3453
Lakhdar, Sami; Berionni, Guillaume; Terrier, François: Superelectrophilicity in Michael-Type Reactions: Water Addition to 4-Nitrobenzodifuroxan
https://www.thieme-connect.de/media/synthesis/201715/i_z0367_ga_10-1055_s-0036-1590839.gif
3460
Helberg, Julian; Marin-Luna, Marta; Zipse, Hendrik: Chemoselectivity in Esterification Reactions – Size Matters after All
https://www.thieme-connect.de/media/synthesis/201715/i_z0305_ga_10-1055_s-0036-1588854.gif
Supporting Information
3471
Moormann, Widukind; Langbehn, Daniel; Herges, Rainer: Solvent-Free Synthesis of Diazocine
https://www.thieme-connect.de/media/synthesis/201715/i_z0341_ga_10-1055_s-0036-1590685.jpg
3476
Sauermann, Nicolas; Loup, Joachim; Kootz, Darius; Yatham, V. Reddy; Berkessel, Albrecht; Ackermann, Lutz: Triazolylidene Ligands Allow Cobalt-Catalyzed C–H/C–O Alkenyl­ations at Ambient Temperature
https://www.thieme-connect.de/media/synthesis/201715/i_z0268_ga_10-1055_s-0036-1590471.gif
Supporting Information
3485
Siebert, Max; Storch, Golo; Rominger, Frank; Trapp, Oliver: Temperature-Controlled Bidirectional Enantioselectivity in Asymmetric Hydrogenation Reactions Utilizing Stereodynamic Iridium Complexes
https://www.thieme-connect.de/media/synthesis/201715/i_z0312_ga_10-1055_s-0036-1588861.gif
Supporting Information
3495
Follet, Elsa; Zipse, Hendrik; Lakhdar, Sami; Ofial, Armin R.; Berionni, Guillaume: Nucleophilicities and Lewis Basicities of Sterically Hindered Pyridines
https://www.thieme-connect.de/media/synthesis/201715/i_z0304_ga_10-1055_s-0036-1590504.gif
Supporting Information
3505
Fernando, Jared E. M.; Levens, Alison; Moock, Daniel; Lupton, David W.: N-Heterocyclic Carbene Catalyzed Transformylation
https://www.thieme-connect.de/media/synthesis/201715/i_z0224_ga_10-1055_s-0036-1588449.gif
Supporting Information

errata

e4
Reissig, Hans-Ulrich; Zimmer, Reinhold: Cyclizations of Alkoxyallenes: Mechanisms, Intermediates, Products – A Personal Account on Solved and Unsolved Problems with Unique Allene Building Blocks