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Synthesis
DOI: 10.1055/a-2402-6757
DOI: 10.1055/a-2402-6757
feature
Aza-BODIPY-Based Bifunctional Photocatalyst for Red-Light-Driven Asymmetric Hydroxylation of β‑Ketoesters
The National Natural Science Foundation of China (22122102, 22271134), Guangdong Provincial Key Laboratory of Catalysis (2020B121201002), Guangdong Pearl River Talent Program (2019QN01Y628), Shenzhen Science and Technology Innovation Commission (RCJC20221008092723013, JCYJ20230807093104009), and Hebei Province Innovation Capability Enhancement Plan Project (22567632H).
Abstract
A novel bifunctional photocatalyst combining an aza-BODIPY and a chiral oxazoline has been developed. This photocatalyst enables the asymmetric hydroxylation of β‑ketoesters under an oxygen atmosphere and irradiation with 18-W red LEDs. This procedure offers a convenient and potentially general approach to obtain enantioenriched α-hydroxy-β-dicarbonyl products. The results reported in this manuscript demonstrate the promise of this new organic photocatalyst design and will help expand the application of BODIPY-based chiral photocatalysts.
Key words
bifunctional photocatalyst - aza-BODIPY - asymmetric catalysis - β‑ketoesters - red-light photocatalysisSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2402-6757.
- Supporting Information
Publication History
Received: 31 May 2024
Accepted after revision: 23 August 2024
Accepted Manuscript online:
23 August 2024
Article published online:
26 September 2024
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