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Synthesis 2010(11): 1777-1780
DOI: 10.1055/s-0029-1218729
DOI: 10.1055/s-0029-1218729
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Facile Atom-Economic Synthesis of Ammonium Diselenophosphinates via Three-Component Reaction of Secondary Phosphines, Elemental Selenium, and Ammonia
Further Information
Received
25 February 2010
Publication Date:
12 April 2010 (online)
Publication History
Publication Date:
12 April 2010 (online)
Abstract
The three-component reaction between secondary phosphines, R2PH [R = Ph(CH2)2, PhCHMeCH2, PhCH2CHMe, 4-t-BuC6H4(CH2)2, 4-MeOC6H4(CH2)2, 2-furyl(CH2)2, 4-pyridyl(CH2)2, 6-Me-3-pyridyl(CH2)2, Ph], elemental selenium, and ammonia proceeds under mild conditions (EtOH-H2O, 53-55 ˚C or EtOH, r.t., 10 min) without the formation of byproducts to give the first representatives of ammonium diselenophosphinates in high yields (up to 96%).
Key words
secondary phosphines - elemental selenium - ammonia - three-component reaction - diselenophosphinates - ammonium salts - phosphinodiselenoic acid
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