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Synthesis 2014; 46(06): 757-760
DOI: 10.1055/s-0033-1338585
DOI: 10.1055/s-0033-1338585
paper
Iron(III) Chloride Catalyzed Formation of Aryl Hydrazides from Electron-Rich Arenes and Azodicarboxylates
Further Information
Publication History
Received: 30 October 2013
Accepted after revision: 19 December 2013
Publication Date:
28 January 2014 (online)
Abstract
Iron(III) chloride-catalyzed direct amination of electron-rich arenes with azodicarboxylates gives the corresponding aryl hydrazides in moderate to good yields within two minutes under mild conditions. This method will serve as an important tool for the synthesis of bioactive nitrogen-containing products and pharmaceuticals.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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For selected recent examples, see:
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For selected recent examples, see: