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Synthesis 2017; 49(08): 1884-1888
DOI: 10.1055/s-0036-1588384
DOI: 10.1055/s-0036-1588384
paper
A Novel Three-Step Tandem Reaction for Efficient Syntheses of Bulky Anthracenyl Esters from 2-Benzylbenzoic Acids
Further Information
Publication History
Received: 21 October 2016
Accepted after revision: 06 December 2016
Publication Date:
08 February 2017 (online)
![](https://www.thieme-connect.de/media/synthesis/201708/lookinside/thumbnails/ss-2016-h0741-op_10-1055_s-0036-1588384-1.jpg)
Abstract
Bulky anthracenyl esters could be efficiently synthesized from 2-benzylbenzoic acids via a novel three-step tandem reaction containing intramolecular Friedel–Crafts acylation, enolization, and esterification. A mechanism for the tandem reaction is proposed.
Key words
tandem reaction - Friedel–Crafts acylation - enolization - esterification - anthracenyl estersSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0036-1588384.
- Supporting Information
- CIF File
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