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Synthesis 1988; 1988(7): 525-529
DOI: 10.1055/s-1988-27624
DOI: 10.1055/s-1988-27624
paper
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Synthese von Bryophyten-Inhaltstoffen 1. Neue Synthesen der Lunularsäure und einiger ihrer Derivate
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Publication History
Publication Date:
18 September 2002 (online)
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New Syntheses of Lunularic Acid and Some of Its Derivatives Efficient and convenient procedures are reported for the synthesis of lunularic acid (2) and for some of its derivatives on a preparative scale starting from the methyl ether 5 or the acetate 12 of ethyl 6-methylsalicylate (4) and introducing the bibenzyl moiety by metalation/ alkylation or by bromination / Wittig reaction/ hydrogenation sequences.