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Synthesis 1999; 1999(4): 593-596
DOI: 10.1055/s-1999-3448
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2-Acyloxy-4,6-dimethoxy-1,3,5-triazine - A New Reagent for Ester Synthesis

Janina E. Kamińska* , Zbigniew J. Kamiński, Józef Góra
  • *Institute of General Food Chemistry, Technical University of Łódź, ul. Stefanowskiego 4/10, 90-924 Łódź, Poland; Fax +48(42)6 36 28 60; E-mail: jekamins@snack.p.lodz.pl
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Publication Date:
31 December 1999 (online)

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2-Acyloxy-4,6-dimethoxy-1,3,5-triazines obtained in reaction between carboxylic acid and 2-chloro-4,6-dimethoxy-1,3,5-triazine were used as acylating agents for the synthesis of esters from primary, secondary, and tertiary alcohols. Because of mild acylation conditions the method could be applied to esterification of labile alcohols with aromatic and aliphatic (also α-branched) acids in good yields.

transesterification - alcoholysis - catalyst - magnesium bromide