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Synthesis 2000; 2000(13): 1936-1943
DOI: 10.1055/s-2000-8229
DOI: 10.1055/s-2000-8229
special topic
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Reptilian Chemistry: Enantioselective Syntheses of Novel Components from a Crocodile Exocrine Secretion
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Publication History
Publication Date:
31 December 2000 (online)
![](https://www.thieme-connect.de/media/synthesis/200013/lookinside/thumbnails/10.1055-s-2000-8229-1.jpg)
Enantioselective syntheses of the two naturally-occurring diastereomers of dianeackerone (1a and 1b) and of a closely related steroidal β-oxo ester (2), characterized from the paracloacal glandular secretion of the African dwarf crocodile, Osteolaemus tetraspis, are described.
enantioselective alkylation - crocodile - dianeackerone - natural products - steroids