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Synlett 2009(17): 2740-2748
DOI: 10.1055/s-0029-1217978
DOI: 10.1055/s-0029-1217978
ACCOUNT
© Georg Thieme Verlag
Stuttgart ˙ New York
Organometallic Strategies for the Synthesis of Conjugated Oligomers
Further Information
Received
19 February 2009
Publication Date:
15 September 2009 (online)
Publication History
Publication Date:
15 September 2009 (online)
Abstract
In this account we report on our contribution to the synthesis of conjugated oligomers with defined structures. The targets of our work are oligoenes, oligophenylenevinylenes, also with fluorinated vinylene units, oligophenylenes, and oligomers with thiophene-arylene or thiophene-anthraquinone units. The synthetic strategies developed in our research group are based on transition-metal-catalyzed coupling reactions. This report is organized according to the synthetic methodologies used (use of vinylsilanes, Stille cross-coupling, copper-promoted homocoupling, and Suzuki-Miyaura cross-coupling) rather than on the basis of the target molecules obtained.
1 Introduction
2 The Use of Vinylsilanes in the Synthesis of Polyenes and Oligophenylenevinylenes
3 Stille Cross-Coupling
4 Copper-Promoted Homocoupling Reaction for the Synthesis of Fluorinated Oligophenylenes
5 Suzuki-Miyaura Cross-Coupling
6 Conclusions
Key words
arylations - oligomerization - boron - tin - cross-coupling
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