Synlett 2022; 33(14): 1448-1452
DOI: 10.1055/a-1817-1038
cluster
Organic Chemistry in Thailand

Accelerated Decomposition of Potassium Permanganate in Ferrocenium Ion as Ferrocenium-Doped Manganese(IV) Oxide for Selective Oxidation of Alcohols

Peerapong Chumkaeo
a   NANOCAST Laboratory, Center for Catalysis Science and Technology (CAST), Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, 272 Rama VI Rd., Ratchathewi, Bangkok 10400, Thailand
b   Preclinical Department, Faculty of Medicine, Bangkokthonburi University, 16/10 Liapkhlong Thawiwatthana Rd., Thawi Watthana, Bangkok 10170, Thailand
,
Thinnaphat Poonsawat
a   NANOCAST Laboratory, Center for Catalysis Science and Technology (CAST), Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, 272 Rama VI Rd., Ratchathewi, Bangkok 10400, Thailand
,
Isti Yunita
a   NANOCAST Laboratory, Center for Catalysis Science and Technology (CAST), Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, 272 Rama VI Rd., Ratchathewi, Bangkok 10400, Thailand
c   Department of Chemistry Education, University Negeri Yogyakarta, Jl. Colombo No. 1, Yogyakarta 55281, Indonesia
,
Natcha Temnuch
a   NANOCAST Laboratory, Center for Catalysis Science and Technology (CAST), Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, 272 Rama VI Rd., Ratchathewi, Bangkok 10400, Thailand
,
Titiya Meechai
a   NANOCAST Laboratory, Center for Catalysis Science and Technology (CAST), Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, 272 Rama VI Rd., Ratchathewi, Bangkok 10400, Thailand
b   Preclinical Department, Faculty of Medicine, Bangkokthonburi University, 16/10 Liapkhlong Thawiwatthana Rd., Thawi Watthana, Bangkok 10170, Thailand
,
Nuttapong Kumpan
a   NANOCAST Laboratory, Center for Catalysis Science and Technology (CAST), Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, 272 Rama VI Rd., Ratchathewi, Bangkok 10400, Thailand
,
Achjana Khamthip
a   NANOCAST Laboratory, Center for Catalysis Science and Technology (CAST), Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, 272 Rama VI Rd., Ratchathewi, Bangkok 10400, Thailand
,
Laksamee Chaicharoenwimolkul Chuaitammakit
d   Chemistry, Faculty of Science and Technology, Suratthani Rajabhat University, 272 Moo 9, Surat-Nasan Rd., Khuntale, Muang, Surat Thani 84100, Thailand
,
Sanoe Chairam
e   Department of Chemistry and Center for Innovation in Chemistry, Faculty of Science, Ubon Ratchathani University, Warinchamrap, Ubon Ratchathani 34190, Thailand
,
Ekasith Somsook
a   NANOCAST Laboratory, Center for Catalysis Science and Technology (CAST), Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, 272 Rama VI Rd., Ratchathewi, Bangkok 10400, Thailand
› Institutsangaben
This research has received funding support from NSRF via the Program Management Unit for Human Resources & Institutional Development, Research and Innovation (Grant number B16F640099).


Abstract

Ferrocenium-doped manganese(IV) oxide (Fc+/MnO2) was synthesized through accelerated decomposition of KMnO4 in the presence of ferrocenium ion (Fc+) generated by concentrated sulfuric acid. The corresponding catalysts enabled highly efficient oxidation of alcohols with aldehyde or ketone.

Supporting Information



Publikationsverlauf

Eingereicht: 14. Februar 2022

Angenommen nach Revision: 05. April 2022

Accepted Manuscript online:
05. April 2022

Artikel online veröffentlicht:
05. Mai 2022

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