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DOI: 10.1055/a-2446-8286
Manganese- and Iron-Catalyzed Carbonylation Reactions: A Personal Account
We thank the financial support from the National Key Research and Development Program of China (2023YFA1507500) and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences (DICP).
Abstract
Transition-metal-catalyzed carbonylative transformations have been widely employed to convert CO gas into valuable carbonyl-containing molecules, mainly using noble metals (Pd, Rh, Ir, Ru) and more recently nickel and other catalysts. Although noble-metal catalysts have the advantage of reaction efficiency, their high-cost has led scientists to explore alternative procedures. Also under these backgrounds, we carried out some studies on nonexpensive metal-catalyzed carbonylative transformations. In this Account, we summarize the carbonylation reactions developed in our research group by using manganese and iron catalysis. These carbonylation reactions proceeded either via SET (single-electron transfer) or TET (two-electron transfer) mechanism.
1 Introduction
2 Manganese-Catalyzed Carbonylation of Alkyl Chlorides
3 Manganese-Catalyzed Carbonylation of Alkyl Iodides
4 Iron/Copper-Catalyzed Carbonylation of Alkyl Bromides
5 Iron-Catalyzed Carbonylation of Alkyl Bromides
6 Iron-Catalyzed Carbonylation of Alkyl-Boronic Pinacol
7 Iron-Catalyzed Aminoalkylative Carbonylative Cyclization of Alkenes
8 Conclusion and Outlook
Key words
carbonylation - manganese catalyst - iron catalyst - single-electron transfer - two-electron transferPublication History
Received: 28 September 2024
Accepted after revision: 21 October 2024
Accepted Manuscript online:
21 October 2024
Article published online:
11 November 2024
© 2024. Thieme. All rights reserved
Georg Thieme Verlag KG
Oswald-Hesse-Straße 50, 70469 Stuttgart, Germany
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