Efficient Zn-Mediated Allylation and Alkylation of Aminals

B. Hatano; K. Nagahashi; T. Kijima

doi:10.1055/s-0028-1087712

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Synfacts 2009(3): 0311-0311
DOI: 10.1055/s-0028-1087712

Metal-Mediated Synthesis

Efficient Zn-Mediated Allylation and Alkylation of Aminals

Contributor(s): Paul Knochel, Andreas J. Wagner
B. Hatano*, K. Nagahashi, T. Kijima
Yamagata University, Yonezawa, Japan

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Publication History

Publication Date:
19 February 2009 (online)

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Significance

In the presence of TMSCl and diisopropylamine, aryl and alkyl aminals react readily with organozinc bromides at room temperature providing the corresponding tertiary amines in good to excellent yields.