Copper-Catalyzed 1,3-Dipolar Cycloaddition of Azomethine
Ylides

C.-J. Wang; G. Liang; Z.-Y. Xue; F. Gao

doi:10.1055/s-0028-1087774

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Synfacts 2009(3): 0303-0303
DOI: 10.1055/s-0028-1087774

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Copper-Catalyzed 1,3-Dipolar Cycloaddition of Azomethine Ylides

Contributor(s): Hisashi Yamamoto, Pingfan Li
C.-J. Wang*, G. Liang, Z.-Y. Xue, F. Gao
Wuhan University, P. R. of China

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Publikationsverlauf

Publikationsdatum:
19. Februar 2009 (online)

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Significance

A novel N,P-ligand is employed in the copper-catalyzed 1,3-dipolar cycloaddition of azomethine ylides giving the substituted pyrrolidine products in high yields and excellent enantioselectivity. Significant improvement of substrate scope over previous studies is realized in this work.