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Synfacts 2009(4): 0418-0418  
DOI: 10.1055/s-0028-1087880
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

Diastereoselective Ti(IV) Enolate Glycosylation

Contributor(s): Hisashi Yamamoto, Zhi Li
G. Jalce, X. Franck, B. Figadère*
Université Paris-Sud and Université de Rouen, France
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Publikationsdatum:
23. März 2009 (online)

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Significance

In this paper the authors described syntheses of achiral N-acetyloxazolidine-2-thiones with different substitution patterns and examined the efficacy of their titanium enolates in the diastereoselective C-glycosylation of lactol acetates.