Abstract
We have evaluated the potential of CuI -doped zeolites
as heterogeneous catalysts for organic synthesis. Such catalysts proved
to be easy to prepare, handle, recover, and recycle. They could
be applied to different synthetic applications, such as [3+2] cycloadditions
of alkynes with either azides or azomethine imines and the homocoupling
of alkynes. These interesting characteristics make them highly attractive
as catalysts for organic chemists, especially with regard to aspects
of ‘green chemistry’.
1 Introduction
2 Synthesis and Structures of CuI -Doped Zeolites
3 CuI -Zeolites as Catalysts in Organic Synthesis
3.1 Cycloadditions: ‘Click in Zeo’
3.2 Cascade Reactions: Substitution and Cycloaddition
3.3 Cycloadditions: Mechanistic Investigations
3.4 Homocoupling of Alkynes
4 Conclusion
Key words
zeolite - copper - catalysis - green
chemistry
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