Synthesis of Briarellins E and F

doi:10.1055/s-0029-1219024

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Synfacts 2010(2): 0135-0135
DOI: 10.1055/s-0029-1219024

Synthesis of Natural Products and Potential Drugs

Synthesis of Briarellins E and F

Contributor(s): Philip Kocienski
O. Corminboeuf, L. E. Overman*, L. D. Pennington
University of California, Irvine, USA

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Publication History

Publication Date:
21 January 2010 (online)

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Significance

The synthesis of briarellins E and F featured a Prins-pinacol rearrangement for assembling the oxacyclic framework (C + D → E) and an intramolecular Nozaki-Hiyama-Kishi reaction to construct the oxacyclononane ring.