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Synfacts 2010(2): 0222-0222
DOI: 10.1055/s-0029-1219062
DOI: 10.1055/s-0029-1219062
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
α-Alkylation of Carbonyl Compounds by Addition of Alcohols to Enol Acetates
Y. Nishimoto, Y. Onishi, M. Yasuda, A. Baba*
Osaka University, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
21. Januar 2010 (online)
Significance
The authors have developed a new procedure for the α-alkylation of aldehydes and ketones that involves the direct use of alcohols and enol acetates in the presence of either InI3, GaBr3 or FeBr3 as catalyst. The reaction is applicable to various types of alcohols and enol acetates.