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Synfacts 2010(2): 0213-0213  
DOI: 10.1055/s-0029-1219064
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Oxidative Amination of Heteroaryl Zinc Reagents Mediated by PhI(OAc)2

Contributor(s): Paul Knochel, Andreas J. Wagner
M. Kienle, C. Dunst, P. Knochel*
Ludwig-Maximilians-Universität, München, Germany
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Publikationsdatum:
21. Januar 2010 (online)

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Significance

The oxidative amination of functionalized heterocycles has been achieved by ­using readily available heterocyclic zinc reagents and lithium amides. Iodobenzene diacetate proved to be a suitable reagent for this oxidative amination.