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Synfacts 2010(5): 0526-0526
DOI: 10.1055/s-0029-1219724
DOI: 10.1055/s-0029-1219724
Synthesis of Heterocycles
© Georg Thieme Verlag
Stuttgart ˙ New York
Palladium-Catalyzed Synthesis of Pyrrolo-Fused Compounds from Nitroarenes
S. P. Gorugantula, G. M. Carrero-Martínez, S. W. Dantale, B. C. G. Söderberg*
West Virginia University, Morgantown, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
22. April 2010 (online)

Significance
A useful palladium-catalyzed, carbon monoxide mediated reductive N-heterocyclization of ortho-styryl nitro-heteroaromatic compounds 1 to afford bicyclic pyrrolo-fused heteroaromatic molecules 2 is described. The scope of the method was reasonably investigated. Bicyclic products were obtained in poor to excellent yields. No cyclization was observed when isoxazole or pyrrole was used as heteroaromates.