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Synfacts 2010(7): 0806-0806
DOI: 10.1055/s-0029-1220032
DOI: 10.1055/s-0029-1220032
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
A Novel Catalyst for Tandem Oxidation and Alkylation
X. Chen, Q. Liu, H.-B. Sun, X.-Q. Yu*, L. Pu*
Sichuan University, Chengdu, P. R. of China and University of Virginia, Charlottesville, USA
Further Information
Publication History
Publication Date:
22 June 2010 (online)
Significance
A novel BINOL-terpyridine-based multitask catalyst was developed for a sequential oxidation and an asymmetric alkylation. A variety of primary alcohols was converted into chiral secondary alcohols with high yield and enantioselectivity.