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Synlett 2011(1): 1-5
DOI: 10.1055/s-0030-1259093
DOI: 10.1055/s-0030-1259093
SYNPACTS
© Georg Thieme Verlag
Stuttgart ˙ New York
Cross-Coupling Chemistry at Mononuclear and Dinuclear Nickel Complexes
Further Information
Publication History
Received
12 October 2010
Publication Date:
16 December 2010 (online)


Abstract
Nickel catalysts have been developed for a wide range of C-C bond formation reactions. Reaction mechanisms proposed for these transformations generally involve catalytic intermediates based on mononickel species. These reactions are reviewed and the possibility of dinickel species active in C-C cross-coupling chemistry is discussed.
Key words
nickel - cross-coupling - alkyl halides - dinuclear mechanism - metal-arene interactions