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Synfacts 2011(2): 0170-0170
DOI: 10.1055/s-0030-1259276
DOI: 10.1055/s-0030-1259276
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Alkene Alkoxycarbonylation Using Novel Chiral Dipalladium Catalysts
T. M. Konrad, J. A. Fuentes, A. M. Z. Slawin, M. L. Clarke*
University of St. Andrews, UK
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
19. Januar 2011 (online)

Significance
Catalytic carbonylation reactions of alkenes are of great importance, providing valuable products from readily available starting materials, often on industrial scale. While many enantio-selective hydroformylation reactions are known, alkoxycarbonylations (hydroesterifications) and hydroxycarbonylations are much less common. The authors present an enantioselective hydroxycarbonylation of styrene and norbornene. The use of novel dimeric palladium phosphane precatalysts is crucial for obtaining high reactivity and enantioselectivity.