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Synfacts 2011(4): 0379-0379
DOI: 10.1055/s-0030-1259630
DOI: 10.1055/s-0030-1259630
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag
Stuttgart ˙ New York
Donor-Acceptor Type Fused Porphyrin-Perylene Monoimides
C. Jiao, K.-W. Huang, C. Chi, J. Wu*
National University of Singapore, Singapore and King Abdullah University of Science and Technology, Thuwal, Kingdom of Saudi Arabia
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
18. März 2011 (online)
Significance
The authors reported the synthesis of doubly or triply fused porphyrin-perylene monoimides with a donor-acceptor-type structure. The hybrids were prepared by the Suzuki cross-coupling followed by FeCl3-mediated intramolecular cyclodehydrogenation in one pot. Activation of both the peri and meta positions of the perylene monoimide was observed.