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Synfacts 2011(5): 0543-0543  
DOI: 10.1055/s-0030-1259777
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Titanium-Mediated Oxidative Arylation of Homoallylic Alcohols

Contributor(s): Paul Knochel, Andreas J. Wagner
K. S. Lee, J. M. Ready*
The University of Texas Southwestern Medical Center, Dallas, USA
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Publikationsdatum:
15. April 2011 (online)

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Significance

Allylic alcohols are shown to undergo a selective trans arylation, if treated with an excess of arylmagnesium bromide in the presence of stoichiometric amounts of titanium isopropoxide.