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Synfacts 2011(5): 0545-0545  
DOI: 10.1055/s-0030-1259785
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Palladium-Catalyzed 1,1-Arylacetoxylation of Terminal Olefins

Contributor(s): Paul Knochel, Andreas K. Steib
A. D. Satterfield, A. Kubota, M. S. Sanford*
University of Michigan, Ann Arbor, USA
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Publikationsdatum:
15. April 2011 (online)

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Significance

A new palladium-catalyzed 1,1-aryl-oxygenation of terminal olefins using organostannanes and hypervalent iodine oxidants is reported. The reaction connects these three components by creating a C-C and a C-O bond as well as a new stereocenter in a single transformation.