Ni-Catalyzed Cross-Couplings of Tertiary Alkyl Grignards
and Aryl Bromides

A. Joshi-Pangu; C.-Y. Wang; M. R. Biscoe

doi:10.1055/s-0030-1260716

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Synfacts 2011(8): 0897-0897
DOI: 10.1055/s-0030-1260716

Metal-Mediated Synthesis

Ni-Catalyzed Cross-Couplings of Tertiary Alkyl Grignards and Aryl Bromides

Contributor(s): Paul Knochel, Andreas K. Steib
A. Joshi-Pangu, C.-Y. Wang, M. R. Biscoe*
The City College of New York, USA

Further Information

Publication History

Publication Date:
20 July 2011 (online)

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Significance

A new Ni-catalyzed Kumada cross-coupling reaction of tertiary alkylmagnesium halides and aryl bromides has been developed. NiCl₂ in combination with a commercially available N-heterocyclic carbene ligand is used as catalytic system.