Room-Temperature Rh-Catalyzed Asymmetric Conjugate Addition

F. Berhal; O. Esseiva; C.-H. Martin; H. Tone; J.-P. Genêt; T. Ayad; V. Ratovelomanana-Vidal

doi:10.1055/s-0030-1260721

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Synfacts 2011(8): 0887-0887
DOI: 10.1055/s-0030-1260721

Metal-Mediated Synthesis

Room-Temperature Rh-Catalyzed Asymmetric Conjugate Addition

Contributor(s): Paul Knochel, Andreas J. Wagner
F. Berhal, O. Esseiva, C.-H. Martin, H. Tone, J.-P. Genêt, T. Ayad, V. Ratovelomanana-Vidal*
Chimie ParisTech, France

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Publication History

Publication Date:
20 July 2011 (online)

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Significance

Two novel atropisomeric diphosphine ligands based on SYNPHOS have been prepared and used in the Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to Michael acceptors at room temperature.