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Synfacts 2011(8): 0885-0885
DOI: 10.1055/s-0030-1260728
DOI: 10.1055/s-0030-1260728
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Amine-Directed Alkyl-Alkyl Suzuki Reactions
Z. Lu, A. Wilsily, G. C. Fu*
Massachusetts Institute of Technology, Cambridge, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
20. Juli 2011 (online)

Significance
This work reports the development of a stereoconvergent aryl amine directed alkyl-alkyl Suzuki coupling. In this protocol, unactivated secondary alkyl chlorides serve as substrates and the desired products are generally obtained with good enantioselectivity using a C 2-symmetric 1,2-diamine ligand.