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Synlett 2011(12): 1649-1653
DOI: 10.1055/s-0030-1260799
DOI: 10.1055/s-0030-1260799
SYNPACTS
© Georg Thieme Verlag
Stuttgart ˙ New York
NHC-NiH Reactions with Simple Olefins: Advances in Hydroalkenylation, Polymerization, and Ionic-Liquid Synthesis
Weitere Informationen
Received
28 December 2010
Publikationsdatum:
21. Juni 2011 (online)
Publikationsverlauf
Publikationsdatum:
21. Juni 2011 (online)
![](https://www.thieme-connect.de/media/synlett/201112/lookinside/thumbnails/10.1055-s-0030-1260799-1.jpg)
Abstract
Various NHC-NiH species have been developed as hydroalkenylation and polymerization catalysts and for ionic-liquid synthesis. This article outlines their key features and connections and highlights the opportunities for using NHC-NiH species in the selective preparation of new geminal disubstituted olefins and how they complement traditional P-NiH technology.
Key words
N-heterocyclic carbene - homogeneous Ni catalysis - geminal disubstituted alkene - regioselective insertion - co-dimer
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