Pd Nanoparticles in the Metal-Organic Framework MIL-101

doi:10.1055/s-0030-1261090

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Synfacts 2011(10): 1142-1142
DOI: 10.1055/s-0030-1261090

Polymer-Supported Synthesis

Pd Nanoparticles in the Metal-Organic Framework MIL-101

Contributor(s): Yasuhiro Uozumi, Yoichi M. A. Yamada, Maki Minakawa
J. Hermannsdörfer, R. Kempe*
Universität Bayreuth, Germany

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Publication History

Publication Date:
20 September 2011 (online)

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Significance

A metal-organic framework MIL-101 with size-controlled Pd nanoparticles (NPs) was prepared. [(η⁵-C₅H₅)Pd(η^³-C₃H₅)] was installed in MIL-101 by metal-organic chemical vapor deposition. Reduction at 21 ˚C (5 bar H₂) gave Pd NPs LL4842 (Æ 2.9 nm) with a narrow size distribution. Reduction at 70 ˚C (70 bar H₂) afforded smaller Pd NPs HH1545 (Æ 1.7 nm).