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Synfacts 2011(12): 1323-1323  
DOI: 10.1055/s-0031-1289329
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

Pd-Catalyzed Asymmetric Allylic Amination

Contributor(s): Hisashi Yamamoto, Jiajing Tan
B.-H. Zheng, C.-H. Ding, X.-L. Hou*
Shanghai Institute of Organic Chemistry and Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, P. R. of China
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Publication History

Publication Date:
18 November 2011 (online)

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Significance

The described methodology allows for the construction of branched allylic amines by Pd-catalyzed allylic amination of monosubstituted allylic substrates with BocNHOMe in high regio- and enantioselectivities.