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Synlett 2012; 23(9): 1271-1282
DOI: 10.1055/s-0031-1290486
DOI: 10.1055/s-0031-1290486
account
Alkynedicobalt Complexes in γ-Carbonyl Cations and Cycloheptynedicobalt Complexes
Weitere Informationen
Publikationsverlauf
Received: 29. November 2011
Accepted after revision: 04. Januar 2012
Publikationsdatum:
29. März 2012 (online)
Abstract
This Account describes our work on highly electrophilic γ-carbonyl cations featuring propargyldicobalt cations, cycloheptynedicobalt complexes, and the interconnection between the two systems.
1 Introduction
2 γ-Carbonyl Cations via Iron Allyl Cations
3 γ-Carbonyl Cations via Propargyldicobalt Cations
3.1 Synthesis of Velloziolide
3.2 Synthesis of Microstegiol
4 Synthesis of Cycloheptynedicobalt Complexes
4.1 Synthesis via γ-Carbonyl Cations
4.2 Cycloheptynedicobalt Complexes via [4+3] Cycloaddition Reactions
4.3 Cycloheptynedicobalt Complexes via Ring-Closing Metathesis
4.4 Cycloaddition Reactions on Cycloheptynedicobalt Complexes
4.5 Cycloheptynedicobalt Complexes via Intramolecular Nicholas Reactions
5 Dehydrotropylium Ion Co2(CO)6 Complex
6 Final Comments
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