Synthesis 2012; 44(17): 2786-2792
DOI: 10.1055/s-0032-1316750
paper
© Georg Thieme Verlag Stuttgart · New York

Chemoselective Reactions of Secondary Phosphine Chalcogenides with Vinyloxyalkylamines: Synthesis of a Novel Family of Functional Phosphinoсhalcogenоic Amides

Nina K. Gusarova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   eMail: boris_trofimov@irioch.irk.ru
,
Pavel A. Volkov
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   eMail: boris_trofimov@irioch.irk.ru
,
Nina I. Ivanova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   eMail: boris_trofimov@irioch.irk.ru
,
Ludmila A. Oparina
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   eMail: boris_trofimov@irioch.irk.ru
,
Nikita A. Kolyvanov
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   eMail: boris_trofimov@irioch.irk.ru
,
Oksana V. Vysotskaya
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   eMail: boris_trofimov@irioch.irk.ru
,
Ludmila I. Larina
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   eMail: boris_trofimov@irioch.irk.ru
,
Boris A. Trofimov*
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation, Fax: +7(3952)419346   eMail: boris_trofimov@irioch.irk.ru
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Publikationsverlauf

Received: 17. Mai 2012

Accepted after revision: 23. Juni 2012

Publikationsdatum:
08. August 2012 (online)


Abstract

The reactions of secondary phosphine сhalcogenides with vinyloxyalkylamines proceed chemoselectively in triethylamine–carbon tetrachloride under mild conditions to give the corresponding phosphinoсhalcogenоic amides bearing vinyloxy moieties in 78–95% yields.