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Synlett 2013; 24(8): 898-902
DOI: 10.1055/s-0032-1318434
DOI: 10.1055/s-0032-1318434
synpacts
What About the Five-Membered Ring? Cyclopenta-fused Polycyclic Aromatic Hydrocarbons as a Building Block for Functional Materials
Further Information
Publication History
Received: 28 January 2013
Accepted: 19 February 2013
Publication Date:
08 March 2013 (online)
Dedicated to Rhett Emmett.
Abstract
There has been recent interest in creating new functional materials based on cyclopenta-fused polycyclic aromatic hydrocarbons (CP-PAH) that can be integrated into organic electronic devices. These five-membered-ring-containing materials are appealing because the electronic properties that are associated with their nonalternate PAH ring structure are not typically accessible by alternate PAH composed solely of six-membered rings. This paper highlights some recent synthetic advances for new CP-PAH systems and describes work from our lab that we believe has helped advance the methodology to create new CP-PAH-containing small molecules and polymeric materials.
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