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Synlett 2013; 24(11): 1311-1315
DOI: 10.1055/s-0033-1338421
DOI: 10.1055/s-0033-1338421
synpacts
Mechanistic Insight to the Reaction Pathway of Aerobic Oxidative C–C Bond Cleavage of α-Hydroxy Ketones
Weitere Informationen
Publikationsverlauf
Received: 22. Februar 2013
Accepted after revision: 25. März 2013
Publikationsdatum:
23. April 2013 (online)
Abstract
A novel transition-metal-free aerobic oxidative C–C bond-cleavage method has been developed. Oxygen, the ideal oxidant, was used as the oxidizing reagent. The dimeric intermediate and 18O-isotopic-labeling control experiments partially disclosed the reaction mechanism.
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