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Synlett 2014; 25(19): 2686-2702
DOI: 10.1055/s-0034-1379230
DOI: 10.1055/s-0034-1379230
account
The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis
Further Information
Publication History
Received: 17 July 2014
Accepted after revision: 07 September 2014
Publication Date:
20 October 2014 (online)
Abstract
This account summarizes our recent work on palladacycles in organic synthesis and describes some unique catalytic properties of palladacycles as transition-metal catalysts for some useful transformations. Asymmetric induction has been realized by using chiral palladacycles as transition-metal catalysts. The influence of the C−Pd bond of palladacycles on their catalytic activity has been revealed. The reaction selectivity can be switched by appropriate choice of an sp2- or sp3-hybridized C,P-palladacycle catalyst.
1 Introduction
2 The Discovery of the Use of Palladacycles as Transition-Metal Catalysts and Their Applications in Asymmetric Catalysis
3 Switch Between Addition and Ring Opening in the Reaction of Oxabicyclic Alkenes with Terminal Alkynes by Catalysis with sp2-C,P- or sp3-C,P-Palladacycles
4 Synthesis of Polysubstituted Furans, Methylenecyclopropanes, and Polycyclic 5H-Benzo[b]azepines through Catalysis by Palladacycles
5 Conclusions
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For some examples of the use of palladacycles as catalysts in coupling reactions, see:
For some examples, see:
For some examples of Ir-, Ni-, or Rh-catalyzed reactions of oxabicyclic alkenes with terminal alkynes, see:
For a recent report on a Pd-catalyzed ring-opening reaction of oxabicyclic alkenes with terminal alkynes, see:
For some examples, see: