An Efficient and Practical Method for Olefin Dihydroxylation

Zhi-bin Luo; Chen Zhao; Jimin Xie; Hong-fei Lu

doi:10.1055/s-0035-1562783

Synthesis, Inhaltsverzeichnis

Synthesis 2016; 48(21): 3696-3700
DOI: 10.1055/s-0035-1562783

psp

An Efficient and Practical Method for Olefin Dihydroxylation

Zhi-bin Luo*

^aSchool of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. of China eMail: luozb@ujs.edu.cn

,

Chen Zhao

^aSchool of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. of China eMail: luozb@ujs.edu.cn

,

Jimin Xie*

^aSchool of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. of China eMail: luozb@ujs.edu.cn

,

Hong-fei Lu*

^bSchool of Biology and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, P. R. of China eMail: zjluhf1979@hotmail.com

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Abstract

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Abstract

An efficient and economic procedure was developed for the dihydroxylation of various olefin derivatives with commercial KMnO₄ as the oxidant in the presence of a quaternary ammonium salt. This practical procedure is suitable for large-scale production of cis-dihydroxy compounds, even those bearing primary and secondary alcohol groups, without overoxidation.

Keyword

dihydroxylation - diols - acrylates - alkenes - potassium permanganate - quaternary ammonium salts

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Referenzen

References

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