Recent Advances in Intermolecular Hydroacylation of Alkenes with Aldehydes through Rhodium Catalysis

Rui Guo; Guozhu Zhang

doi:10.1055/s-0037-1610141

Synlett, Inhaltsverzeichnis

Synlett 2018; 29(14): 1801-1806
DOI: 10.1055/s-0037-1610141

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Recent Advances in Intermolecular Hydroacylation of Alkenes with Aldehydes through Rhodium Catalysis

Rui Guo

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. of China eMail: guozhuzhang@sioc.ac.cn

,

Guozhu Zhang *

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. of China eMail: guozhuzhang@sioc.ac.cn

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Abstract

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Abstract

The rhodium-catalyzed intermolecular hydroacylation of alkenes with aldehydes is an atom-economical method for the synthesis of ketones. Here, we give a brief review on its development and we highlight recent advances in chelating strategies for the stabilization of acyl rhodium species by coordinative saturation.

Key words

rhodium catalysis - hydroacylation - alkenes - aldehydes - chelation - coordinative saturation

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Referenzen

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