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Synlett 2019; 30(03): 257-262
DOI: 10.1055/s-0037-1610338
DOI: 10.1055/s-0037-1610338
synpacts
Hypervalent Iodine Chemistry as a Platform for Aerobic Oxidation Catalysis
The authors thank Texas A&M University and the Welch Foundation (A-1907) for financial support.Weitere Informationen
Publikationsverlauf
Received: 12. Oktober 2018
Accepted after revision: 05. November 2018
Publikationsdatum:
11. Dezember 2018 (online)
Abstract
Here, we highlight the recent development of aerobic oxidation catalysis via hypervalent I(III) and I(V) intermediates. The described chemistry intercepts reactive intermediates generated during aldehyde autoxidation to accomplish the oxidation of aryl iodides. The aerobically generated hypervalent iodine intermediates are utilized to couple an array of substrate functionalization chemistry to the reduction of O2.
1 Introduction
2 Chemistry of Aerobically Generated I(III) Intermediates
3 Chemistry of Aerobically Generated I(V) Intermediates
4 Conclusions
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