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Synthesis 2021; 53(01): 51-64
DOI: 10.1055/s-0040-1707234
DOI: 10.1055/s-0040-1707234
short review
Recent Advances in Copper-Catalyzed Radical C–H Bond Activation Using N–F Reagents
We thank Ministerio de Economía y Competitividad (MINECO) (No. CTQ2017-82893-C2-1-R) and Universidad de Huelva (No. PO FEDER 2014-2020 UHU-1254043) for grants.Weitere Informationen
Publikationsverlauf
Received: 10. Juni 2020
Accepted after revision: 07. Juli 2020
Publikationsdatum:
25. August 2020 (online)
Abstract
This Short Review is aimed at giving an update in the area of copper-catalyzed C–H functionalization involving nitrogen-centered radicals generated from substrates containing N–F bonds. These processes include intermolecular Csp3–H bond functionalization, remote Csp3–H bond functionalization via intramolecular hydrogen atom transfer (HAT), and Csp2–H bond functionalization, which might be of potential use in industrial applications in the future.
1 Introduction
2 Intermolecular Csp3–H Functionalization
3 Remote Csp3–H Functionalization
4 Csp2–H Functionalization
5 Conclusion
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